Electron Spin Resonance Spectrometer ESR-105

• FET based marginal R.F. Oscillator
• Digital display of frequency
• Excellent peaks display
• Digital display of Helmoltz Coil Current
• Compatible with general purpose CRO in X-Y mode

In recent years Magnetic Resonance has developed into a very useful and powerful tool in solid state research. In this method, use is made of the Zeeman interaction of the magnetic dipoles associated with the nucleus or electron, when placed in an external magnetic field. Accordingly, they are identified as NMR (Nuclear Magnetic Resonance) or ESR (Electron Spin Resonance). This form of spectroscopy finds many applications in the investigation of crystal structures, environmental effects, dynamic effects, defects in solids and in many diverse branches of Physics, Chemistry and Biology.

Elementary Magnetic Resonance
We know that the intrinsic angular momentum (spin) of the electron S – couples with the orbital angular momentum of the electron L– to give a resultant J – and this coupling gives rise to the ‘fine structure’ of the spectra. Further, under the influence of an external magnetic field (H) each of the level will split into (2j+1) sublevels (Zeeman effect) and the splitting of a level will be

∆E = (gμ0H)mj
where μ0 is the Bhor magneton, g is the Lande’ g-factor and mj is the magnetic quantum number. As can be seen, the splitting is not same for all levels; it depends on the J and L of the level (s=1⁄2 always for one electron). However, the sublevels will split equally by an amount
∆E = gμ0H or = hν0
where ν0 is the frequency of the system. Now if the electron is subjected to a perturbation by an oscillating magnetic field with its direction perpendicular to the static magnetic field and its frequency ν1 such that the quantum hν1 is equal to E=hν0, we say that there is a resonance between ν1 and ν0. This will induce transition between neighbouring sublevels (mj = ±1) and in turn will absorb energy from oscillating field. Thus, at resonance, we get a peak due to the absorption of energy by the system.


Experimental Technique
If we consider a free electron and substitute the proper value of constants in the equation: g = 2.00, μ0 = 0.927X1020 erg/gauss & h = 6.625 X l0-27 erg sec, we get
ν0/H0 = 2.8MHz/gauss
That is ESR can be observed at radio frequencies in a magnetic field of a few gauss or in the microwave region in a magnetic field of a few kilogauss. The latter alternate has many advantages: improved signal-to-noise ratio, high resolution etc. and is always preferred for accurate work, though it is very sophisticated and expensive. However, if the basic understanding of the subject is the main criteria as is usually the requirement of class room experiments, the observation of ESR in low magnetic field and in a radio frequency region makes it a lot simple, inexpensive and within the reach of every post-graduate laboratory.

Description of the ESR Spectrometer
A block diagram of the ESR Spectrometer is given below in Fig. 1, and a brief description follows.

Basic Circuit
The first stage of the ESR circuit consists of a critically adjusted (marginal) radio frequency oscillator with 4-digit frequency display. This type of oscillator is required here, so that the slightest increase in its load decreases the amplitude of oscillation to an appreciable extent. The sample is kept inside the tank coil of the oscillator, which in turn, is placed in the 50Hz magnetic field, generated by the Helmholtz coils. At resonance, i.e. when the frequency of oscillation equal to the Larmour’s frequency of the sample, the oscillator amplitude registeres a dip due to the absorption of power by the sample. This obviously, occurs periodically four times in each complete cycle of the supply voltage. The result is an amplitude modulated carrier which is then detected using a FET demodulator and amplified by an op-amp circuit.




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